The physical properties of the lanthanide (4f) and actinide (5f) elements (Ce-Lu and Th-Lr) vary dramatically as one traverses the groups from low-Z to high-Z. The properties of any one metal can be changed in a similar manner by the application of pressure, and many of these elements undergo a sequence of structural phase transitions accompanied by changes in electronic structure. We have recently made significant progress in unravelling the complex structural sequences seen in Pr and Eu under pressure at room temperature (both of which were PhD projects), and now plan to extend these studies to very much higher pressures and temperatures.
The project will involve diamond anvil cell experiments at synchrotron sources in the UK, France and Germany, and may also involve dynamic-compression studies at laser sources in the UK and US. An exciting new development in DAC research is the utilisation of X-ray Free Electron Lasers (XFELs), such as the European-XFEL, to make dynamic diffraction measurements at P-T conditions previously unattainable. We expect this project to make pioneering measurements using this technique.
This project will be conducted in collaboration with AWE Aldermaston, and the has additional CASE or iCASE studentship support, which offers an enhanced stipend, additional funding to attend conferences and beamtime, and an equipment/consumables budget.
- Professor Malcolm McMahon (School of Physics & Astronomy, University of Edinburgh)
The project supervisor welcomes informal enquiries about this project.
Find out more about this research area
The links below summarise our research in the area(s) relevant to this project:
- Find out more about Extreme Conditions.
- Find out more about the Institute for Condensed Matter and Complex Systems.
- Find out how to apply for our PhD degrees.
- Find out about fees and funding and studentship opportunities.
- View and complete the application form (on the main University website).
- Find out how to contact us for more information.